15529-49-4 umxholo wesinyithi 10.5% tris(triphenylphosphine)ruthenium(ii) chloride
Iintshayelelo
Izixhobo zentsimbi ezixabisekileyo ziziintsimbi ezibekekileyo ezisetyenziswa kakhulu kwishishini lemichiza ngenxa yokukwazi kwazo ukukhawulezisa inkqubo yeekhemikhali.Igolide, ipalladium, iplatinum, irhodium, kunye nesilivere yeminye yemizekelo yeentsimbi ezixabisekileyo.Izixhobo zentsimbi ezixabisekileyo zezo zibandakanya i-nano-scale yexabiso elixabisekileyo le-nano-scale exhaswa kwindawo ephakamileyo njengekhabhoni, i-silica, kunye ne-alumina.Ezi catalysts zinezicelo ezininzi kumashishini ahlukeneyo.I-catalyst nganye yentsimbi exabisekileyo ineempawu ezizodwa.Ezi catalysts zisetyenziswa ikakhulu kwi-organic synthesis reactions.Izinto ezinje ngokukhula kwemfuno evela kumacandelo okusetyenziswa kokuphela, iinkxalabo zokusingqongileyo kunye neziphumo zabo zomthetho ziqhuba ukukhula kwemarike.
Iipropati ze-catalysts zentsimbi ezixabisekileyo
1.Umsebenzi ophezulu kunye nokukhethwa kweentsimbi ezixabisekileyo kwi-catalysis
Izixhobo zentsimbi ezixabisekileyo zibandakanya i-nano-scale yentsimbi exabisekileyo esasazeke kakhulu kwiinkxaso ezinomgangatho ophezulu onjengekhabhoni, i-silica, kunye ne-alumina.Amasuntswana esinyithi esikali se-nano abhengeza ngokulula i-hydrogen kunye neoksijini emoyeni.Ihydrogen okanye ioksijini iyasebenza kakhulu ngenxa adsorption yayo dissociative ngokusebenzisa d-electron of ngaphandle kweqokobhe leathom zentsimbi exabisekileyo.
2.Uzinzo
Iintsimbi ezixabisekileyo zizinzile.Ayenzi lula iioksidi nge-oxidation.Iioksidi zesinyithi ezixabisekileyo, kwelinye icala, azinzanga.Iintsimbi ezixabisekileyo azinyibiliki lula kwi-asidi okanye kwisisombululo sealkaline.Ngenxa yokuzinza okuphezulu kwe-thermal, i-catalyst yentsimbi exabisekileyo isetyenziswe njengezixhobo zokucoca igesi ephuma kwiimoto.
Igama lemveliso | Tris(triphenylphosphine)ruthenium(II) chloride | |
Inombolo yeCAS. | 15529-49-4 | |
Into | Umgangatho wangaphakathi wendlu | Iziphumo |
Imbonakalo | Umgubo wekristale emnyama | Iyahambelana |
Uvavanyo / Ru | ≥10.0% | Iyahambelana |
Indawo yokunyibilika | 159ºC | Iyahambelana |
Ukunyibilika | Ayinyibiliki emanzini, etha kunye ne-n-hexane.Inyibilika kancinane kwi-methanol, i-ethanol, i-acetone, i-ethyl acetate, i-chloroform kunye ne-toluene.I-ecomposed kalula emoyeni. | Iyahambelana |
Ubunyulu | ≥99% | Iyahambelana |
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